Physical Chemistry

Book Description

Ira N. Levine's fifth edition of Physical Chemistry provides students with an in-depth fundamental treatment of physical chemistry. At the same time, the treatment is made easy to follow by giving full step-by-step derivations, clear explanations and by avoiding advanced mathematics unfamiliar to students. Necessary math and physics have thorough review sections. Worked examples are followed by a practice exercise.

Customer Reviews:

Very good introduction to physical chemistry.......2007-07-23

A previous reviewer stated that physical chemistry is complicated. As a retired NASA researcher with 44 years experience specializing in physical chemistry I readily acknowledge that physical chemistry can be a very challenging subject. But, personally, I have also found it to be immensely fascinating and rewarding. There are several good textbooks on physical chemistry but, in my opinion, none is better than this one. Levine has done a very good job of presenting the material contained in an understandable fashion without compromising scientific rigor.

An earlier reviewer stated that this book is full of inaccuracies, but I strongly disagree with this statement. One example of an alleged inaccuracy which this reviewer cited is Levine`s statement that, at the velocity of light, photons have mass. This is a true statement; photons do indeed have both mass and momentum and thus can cause pressure on objects they strike. I beg you not to be biased against this outstanding book by this flawed review.

The topic of physical chemistry -- in which chemistry, physics, and mathematics overlap and interact -- clearly does not appeal to everyone. Even many chemists shun the rigors of physical chemistry as much as possible. But for those studying this important subject, I highly recommend this book. And some of you may even come to love this fascinating subject as I do.

for those who don't like Levine.......2007-04-25

If you want the most student friendly book get Physical Chemistry , 4/e by Laidler, Meiser, Sanctuary, ISBN 061815292X.

Description on their website says "With its clear explanations and practical pedagogy, Physical Chemistry is less intimidating to students than other texts, without sacrificing the mathematical rigor and comprehensiveness necessary for a junior-level physical chemistry course. The text's long-standing reputation for accessible writing provides clear instruction and superior problem-solving support for students." I second that.

see my review here Physical Chemistry I mention the alternatives as well.

Terrible semester.......2007-03-31

Physical Chemistry is complicated, there is no way of getting around that. This book will go through the derivations, but never include units. That is a huge problem.

Terrible. Absolutely terrible........2006-09-24

I don't know why so many other people think this book is good. I feel just the opposite.

First, it is filled with factual inaccuracies. Let me quote just one howler, from page 604. "At speed c, the photon has a nonzero mass m." Yes, you heard right, Dr. Levine thinks photons have mass. He then goes on to give an incorrect statement and explanation of the De Broglie wavelength. (Among other things, he uses "mv" instead of momentum, which is of course true only in the case of Newtonian mechanics with massive particles. Sigh.) These gaffes are rarely typos, they are generally the sort of thing which someone with a fundamental understanding of the underlying physics cringes at.

Second, Levine is incapable of going a paragraph without interrupting himself. Given the choice of stating something simply, or filling a paragraph with fifteen references (placed in the text, not in footnotes) and a few asides, he always goes for the latter. References are a fine thing, but placing them inside the text and doing it constantly interrupts the reader's thinking.

Taking an example a few pages earlier in the text, it is not sufficient for Levine to start to explain the photoelectric effect, he has to add in a few lines about practical applications of photocells. All fine and well, but it distracts from the flow of the logic, and frankly the applications of photocells aren't germane to what is being taught here, which is that light is quantized. Levine can never resist the temptation to add a little aside -- there are even spots in the book where he interrupts his own interruptions.

Third, Levine is also incapable of writing without making what he discusses somehow seem meaningless and uninteresting. Take thermodynamics. In the hands of a bad author, thermodynamics can seem like a swirling vortex of formula manipulations, but if you read, say, Enrico Fermi's pamphlet from the 1930s, you instead feel as though you're seeing the power of a few ideas applied rigorously to an interesting domain -- you feel the relevance of the topic to the world and you feel the sparkle of the author's intellect. Levine takes this same topic and makes it feel like an endless parade of noise.

Indeed, Levine can take all sorts topics that are full of inherent interest and relevance and make them seem utterly abstract, boring and lifeless. In order to cover up for this, he throws in lots of asides (see above) and the occassional several paragraph digression about the life of some famous scientist. Sadly, you don't make a topic more "interesting for the kids" by throwing in random asides and distractions -- you do it by knowing how to teach. A good teacher can make anything interesting -- a bad one can't make up for it by doing a few juggling tricks.

Between Levine's self-interruptions, asides and dry presentation, somehow the length of the text always seems an order of magnitude longer than necessary to explain any given subject. I often mentally scream "get to the point already!" as I read.

There is also the question of order of presentation. Honestly, I think that starting a discussion of thermodynamics without first at least glossing to the kinetic theory of gases is a mistake. Abstraction has to be tempered with good mental models of what is going on and why it is going on or the student becomes lost. Even a couple of pages showing that the Ideal Gas Law is an emergent result of a simple classical mechanical model would ground the student better to the material. This sort of thing happens over and over in Levine, with discussion being often both too rigorous and unfounded in basic principles at the same time -- quite a trick to pull off.

Levine's text is, of course, in its fifth edition. Presumably, had the earlier revision been left alone, sales might have flagged as used copies from bored students uninterested in holding on to them filled the market. The publishers have therefore done the usual thing and produced trivial updates every few years to assure that used copies become worthless. Does this new fifth edition come with snazzy new diagrams and all the other stigmata of the modern textbook industry? No. The diagrams in the text -- a text you pay a kings ransom for -- were clearly done in MacDraw and MacPaint in the mid-1980s. I am not that upset about this -- I just find it another irritation. Truthfully, I don't need snazzy illustrations -- my favorite physics and chemistry texts are often decades old -- but if you're going to pretend that you're doing a new edition for some reason other than to keep your sales numbers up, at least have the decency to spend a small amount of money on production to keep up appearances. Milking the students is an embarrassment, especially at the inflated price this book commands.

Oh, and did I mention that the book is insanely heavy? That's not a small thing if you have to haul it around a campus constantly.

As I said, I don't know why other reviewers like this book so much. I'm a confirmed science geek who loves reading science texts for their own sake and I'm having a great deal of difficulty reminding myself that this text (which is being used for a class I'm taking) is not reason enough to find the entire subject of physical chemistry an unbearably boring waste of time -- the topic is in fact interesting, it is this book which is the problem.

To survive the course I'm taking with my mind intact, I've used a succession of small texts by people like Fermi and Pauli. The contrast between people who understand a topic well enough to explain it clearly and simply and the people like Levine that churn out heavy uninteresting textbooks is striking. If you're a professor considering the use of this book, please, please, please don't do it. Find something else. there has to be a decent book on this topic out there somewhere.

As a final comment, let me say this is not the worst text I've ever used. That would be H.J. Pain's "The Physics of Vibrations and Waves". To damn Dr. Levine with faint praise, this book doesn't even come close to being as bad as that other text.

Great Book.......2006-04-22

I took both semesters of P.Chem, failing the first because I took way too many upper level Chem Classes & working as well as a weak background in Calc 3. After studying Calc III by myself over the summer and retaking the class, I am able to absorb so much more and I'm ripping a new one in this class. It is truly an amazing book. Having a solid math background helps one to 'connect the dots' so-to-speak whenever Dr. Levine makes these 'shortcuts'. Tons of worked examples, difficult yet definitely possible homework problems and an acutual intelligent sense of humor are woven into the this book making an extremely complex and difficult subject..... engaging, lol. I spend close to 40hrs. per test and I'm thankful I'm putting myeself through this. Great book, just make sure you have a solid understanding of partial diff eqns. and complex algebra before you take it. Not meant for the weak of mind.

Electronic Structure: Basic Theory and Practical Methods

Average customer rating:

A Gr8 Book on DFT Concepts
Excellent book
Not impressive
Outstanding

Electronic Structure: Basic Theory and Practical Methods
Richard M. Martin
Manufacturer: Cambridge University Press
ProductGroup: Book
Binding: Hardcover

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ASIN: 0521782856

Book Description

The study of the electronic structure of materials is at a momentous stage, with the emergence of new computational methods and theoretical approaches. This volume provides an introduction to the field and describes its conceptual framework, the capabilities of present methods, limitations, and challenges for the future. Many properties of materials can now be determined directly from the fundamental equations of quantum mechanics, bringing new insights into critical problems in physics, chemistry, and materials science.

Customer Reviews:

A Gr8 Book on DFT Concepts.......2007-07-05

I like this book and would recommend it to any beginner into density functional theory. It explains all the modern electronic structure techniques in a rather simple language. Its much more easier and quicker than going into hundreds of papers and not knowing where to start.

The biggest issue with this book is a rather poor organisational structure to the book. That's why I've given it a 4/5 rating. There are some concepts that have been easily thrown in at the end, into the appendices.. and having to turn pages too frequently can be annoying.

But the good work has been done & I'd ask Mr Martin to re-organise the content.

This book has the potential to be a classic.

Excellent book.......2006-03-21

As a graduate student attempting to learn density functional theory and its use in computer programmes, I have found this book to be an excellent addition to my library. Well structured and written.

Not impressive.......2005-06-30

Although the topics the book embrasses are current and essential for practising chemists, physisists and materials scientists the pedagogic care with which it explains some of the topics is poor.

The author makes the assumption that the reader is familiarized with the heavy mathematical formalism and notation which is commonplace in specialized physics articles but fails to remember that graduate students that don't have a physics background, and come from other schools of thought such as chemistry, biochemistry or materials science, might be target readers.

For instance the book's introduction to Hartree-Fock theory must be the most complicated I've ever seen with constant recourse to Dirac's delta function (without even revealing its presence, stating simply that it should be there). The link between DFT and statistical thermodynamics although interesting is not essential for the heart of the discussion. Some classic program applications like Siesta are presented but you get the feeling that it's just for show off.

All in all if you're a physicist with some years of experience in the field of planewave computation you might find the book interesting.

Otherwise if you're a beginner like me forget it! The book by Efthimios Kaxiras (Atomic and Electronic Structure of Solids) is more revealing and pedagogic and supplies every detail in the mathematical formalism. Some physicists with a more chemical sensitivity such as Harrison, chemists such as Roald Hoffmann, Jeremy Burdett or Michael Springborg or materials scientists like Adrian Sutton or David Pettifor are better suited for the novice.

Outstanding.......2004-07-07

This book was recommended to me to help me in my research, and has turned out to be one of the best recommendations I have ever received. This is a great book; by far the best I have come across on the topic of computing the properties of condensed phase materials by quantum mechanical simulations. Here are the reasons why.

1. The chapters are well laid out and one chapter flows neatly to the next.

2. The math is kept to a minimum; the author makes a point of communicating important principles and ideas in concise sentences without resorting to derivations. This is ideal for engineers like me; who by training do not know that much math as compared to physicists who specialize in the solid state.

3. Important ideas are clarified up front. Many texts will lead the reader through long and windy paths of proofs and logic before arriving at the conclusion; thereby losing their reader in the process. Not here; important points are stated clearly at the beginning and at the end of each section.

4. Compare, contrast, and context. There are many ideas, models, approximations, and theorems that have been developed in the past century related to electronic structure. Many of these are closely related to each other in their inspiration, derivation, practice, and/or applications. This book makes the connections between the different concepts. For a non-expert reading through the electronic structure literature, terms like APW, OPW, PAW, LAPW, LMTO, etc... can be quite confusing if not placed within an overriding context. This book provides that context.

5. Good use of appendices. Electronic structure is a lot like politics; most practicioners in either field did not receive formal educations in the subject, but instead got into it under the apprenticeship of other people. This is reflected by a lot of literature by those who succeeded in the field; most of it good in showing of the authors' achievements, but generally useless in preparing the next generation of practicioners. For electronic structure, this is manifested by the many books that require prior knowledge of quantum, thermo, crystallography, mat sci, etc.. In effect, these books were written by experts to be read by other experts. Not this book. Basic ideas are kept in the text; and specific proofs and derivations are kept in the appendices. The result is a text that is much easier to read than most others.

6. The book is concept driven; not application driven. Most texts in materials simulations are actually a compilation of chapters written independently by multiple authors. Each chapter might be given a general title; but the text will be bias towards the research of its authors. For example, a chapter on surface calculations might focus entirely on adsorption, or relaxation/reconstruction, or optical properties; but surely not touching all these subjects. This book does not do this; each chapter is driven by basic concepts, and one concept leads to the next.

Book Description

A Practitioner's Handbook for Real-Time Analysis: Guide to Rate Monotonic Analysis for Real-Time Systems contains an invaluable collection of quantitative methods that enable real-time system developers to understand, analyze, and predict the timing behavior of many real-time systems. The methods are practical and theoretically sound, and can be used to assess design tradeoffs and to troubleshoot system timing behavior. This collection of methods is called rate monotonic analysis (RMA).
The Handbook includes a framework for describing and categorizing the timing aspects of real-time systems, step-by-step techniques for performing timing analysis, numerous examples of real-time situations to which the techniques can be applied, and two case studies.
A Practitioner's Handbook for Real-Time Analysis: Guide to Rate Monotonic Analysis for Real-Time Systems has been created to serve as a definitive source of information and a guide for developers as they analyze and design real-time systems using RMA. The Handbook is an excellent reference, and may be used as the text for advanced courses on the subject.

Customer Reviews:

A must-have book for Real-Time system designers/programmers.......1998-07-21

This book is a rare commodity in the area of Real-Time systems. While there are several books on programming in general and object oriented methods in specific for real-time and embedded developers, few approach the subject from timing prodictability point of view.

In several ways, this book has first appeared way ahead of its time. When the processing capacity itself was not available, several embedded developers were more concerned about optimizing their applications for that elusive 'speed' than being worried about building fully predictable systems using proven design methodologies geared towards guaranteeing timing predictability, which inheretly introduce certain inefficiencies in common perception. Therefore, these techniques were deemed to be applicable to only those exotic world of 'hard-real time' systems such as defense, nuclear and not to mere mortals.

With modern processors becoming more and more powerful and devices being targeted to mass markets (e.g! ., set-top boxes, personal communication devices, home automation etc) the market is ready to demand (and of course, get) timing predictability out of embedded devices. Developers therefore need standard books like this and standard software tools (e.g., TimeWiz) to meet this shifting paradigm.

Book Description

This book collects state-of-the-art research and technology for design, analysis, construction and maintenance of textile and inflatable structures.

Textile composites and inflatable structures have become increasingly popular for a variety of applications in – among many other fields – civil engineering, architecture and aerospace engineering. Typical examples include membrane roofs and covers, sails, inflatable buildings and pavilions, airships, inflatable furniture, airspace structures etc.

The book contains 18 invited contributions written by distinguished authors who participated in the International Conference on Textile Composites and Inflated Structures held in Barcelona from June 30 ^th to July 2 ^nd, 2003. The meeting was one of the Thematic Conferences of the European Community on Computational Methods in Applied Sciences (ECCOMAS).

The different chapters discuss recent progress and future research directions in membrane and inflatable structures built with new textile composite materials. Approximately half of the book focuses on describing innovative numerical methods for structural analysis of such structures, such as new nonlinear membrane and shell finite elements. The rest of the chapters present advances in design, construction and maintenance procedures.

Customer Reviews:

Not received.......2007-01-11

I have not received the book.

Best regards.

Dario Ravasi

Optical Properties of Metal Clusters (Springer Series in Materials Science)

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Optical Properties of Metal Clusters (Springer Series in Materials Science)
Uwe Kreibig , and Michael Vollmer
Manufacturer: Springer
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Binding: Hardcover

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ASIN: 3540578366

Book Description

Optical Properties of Metal Clusters deals with the electronic structure of metal clusters determined optically. Clusters - as state intermediate between molecules and the extended solid - are important in many areas, e.g. in air pollution, interstellar matter, clay minerals, photography, heterogeneous catalysis, quantum dots, and virus crystals. This book extends the approaches of optical molecular and solid-state methods to clusters, revealing how their optical properties evolve as a function of size. Cluster matter, i.e. extended systems of many clusters - the most frequently occuring form - is also treated. The combination of reviews of experimental techniques, lists of results and detailed descriptions of selected experiments will appeal to experts, newcomers and graduate students in this expanding field.

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Preserving Digital Information
Henry M. Gladney
Manufacturer: Springer
ProductGroup: Book
Binding: Hardcover

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ASIN: 3540378863

Book Description

Cultural history enthusiasts have asserted the urgent need to protect digital information from imminent loss. Without action, much of what has been created in digital form is likely to become unusable. Although a decade has already elapsed since this challenge was clearly articulated, nobody has described a complete procedure for preventing such loss – until now.

Leading industry consultant Henry M. Gladney outlines a technical solution and justifies its correctness and optimality. His presentation focuses on long-term digital preservation principles as a basis for producing the software that will be needed. The method described will work for any kind of digital document, multimedia file, business record collection, or scientific information, and is believed to be optimal with respect to both the quality of the preserved information and end-user convenience. Additionally, Dr. Gladney explains the requirements of the related software, and sketches how to implement it.

Preserving Digital Information presents an up-to-date description of its field, together with a solution for all technical problems identified in the pertinent professional literature. It is for archivists, research librarians, and museum curators who need to understand digital technology in order to manage their institutions; software engineers and computer scientists whose work requires sound information about digital preservation; and attorneys, medical professionals, government officials, and business executives who depend on the long-term reliability of digital records.

Quantum Chemistry of Solids: The LCAO First Principles Treatment of Crystals (Springer Series in Solid-State Sciences)

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Quantum Chemistry of Solids: The LCAO First Principles Treatment of Crystals (Springer Series in Solid-State Sciences)
Robert A. Evarestov
Manufacturer: Springer
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Binding: Hardcover

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ASIN: 3540487468

Book Description

Quantum Chemistry of Solids delivers a comprehensive account of the main features and possibilities of LCAO methods for the first principles calculations of electronic structure of periodic systems. The first part describes the basic theory underlying the LCAO methods applied to periodic systems and the use of wave-function-based (Hartree-Fock), density-based (DFT) and hybrid hamiltonians. The translation and site symmetry consideration is included to establish connection between k-space solid-state physics and real-space quantum chemistry methods in the framework of cyclic model of an infinite crystal. The inclusion of electron correlation effects for periodic systems is considered on the basis of localized crystalline orbitals. The possibilities of LCAO methods for chemical bonding analysis in periodic systems are discussed. The second part deals with the applications of LCAO methods for calculations of bulk crystal properties, including magnetic ordering and crystal structure optimization. The discussion of the results of some supercell calculations of point defects in non-metallic solids and of the crystalline surfaces electronic structure illustrates the efficiency of LCAO method for solids.

Electronic Structure and the Properties of Solids: The Physics of the Chemical Bond

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Use it as a paper weight.
Without parallel in Materials Science literature
Essential book for condensed matter physicists

Electronic Structure and the Properties of Solids: The Physics of the Chemical Bond
Walter A. Harrison
Manufacturer: Dover Publications
ProductGroup: Book
Binding: Paperback

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ASIN: 0486660214

Book Description

This innovative text offers basic understanding of the electronic structure of covalent and ionic solids, simple metals, transition metals and their compounds. It also explains how to calculate dielectric, conducting, and bonding properties for each. Includes a useful Solid State Table of the Elements.

Customer Reviews:

Use it as a paper weight........2006-11-27

As a scientist who went thru the rigors of getting a PhD in an American public university, I have noticed many subtle but inefficient practices. One of the worst goes as follows. A certain promising doctoral student starts on his (or her) research. His advisor hands him a classic text to read. Said text is nigh incomprehensible, but our prodigal student endeavors and comes to gradually understand the text and apply it to his studies. He graduates, begins his career and eventually gets that tenured position. Years later when he supervises his first graduate student, he imparts said text upon a new sufferer and the process begins anew. This book by W. A. Harrison is such a text. It is extremely hard to read, the words are small, there are few images or graphs or plots, and the examples are not geared for the computer age. But, because this book came out when solid state simulations began to spread in use and multiple free codes came about, it was read and used by many scientists and apprentices. Nowadays, there are dozens of much better books that are much easier to read and understand. Yet I still encounter this text being used. Why? Because many academics fought thru it, are proud of the feat, and somehow intend their trainees to do the same.

I read this book after reading thru over a dozen other books in the same subject, and found this to be the hardest and least understandable. This book is often considered the Bible of electronic structure simulations. This is a correct statement in the worst sense possible because the number of people who understand the Bible is much less than those who swear by it; i.e. very similar to this book. Overall, I do not recommend buying it or reading it. Its only redeeming quality is the exhaustive number of equations.

Without parallel in Materials Science literature.......2002-01-23

This book has no parallel in the literature of theoretical materials science. The information contained in the book allows first principle calculations of properties of important technological materials like perovskite oxides, semiconductors, etc. I would suggest the reader to consult the papers by R. Haydock and others in Solid State Physics, vol.35 of 1980 to
complemment the methods presented in the book.

Essential book for condensed matter physicists.......2000-06-07

If you are studying the solid state physics, it is a necessary book for you. It covers various properties of almost all kinds of solid state materials and shows pretty new experimental data from reliable sources. This book also starts with a clear introduction in each chapter so that even for a beginner, it is easy to read. This book will be a good reference book for you to find out the definition of terminologies in this field. Personally, I use this book as a referece frequently.

This book is definitely not a book you can read through quickly but a book where you find out information through your life.

Book Description

Fault Covering Problems in Reconfigurable VLSI Systems describes the authors' recent research on reconfiguration problems for fault-tolerance in VLSI and WSI Systems. The book examines solutions to a number of reconfiguration problems.
Efficient algorithms are given for tractable covering problems and general techniques are given for dealing with a large number of intractable covering problems.
The book begins with an investigation of algorithms for the reconfiguration of large redundant memories. Next, a number of more general covering problems are considered and the complexity of these problems is analyzed. Finally, a general and uniform approach is proposed for solving a wide class of covering problems.
The results and techniques described here will be useful to researchers and students working in this area. As such, the book serves as an excellent reference and may be used as the text for an advanced course on the topic.

Electronic Structure and Properties of Transition Metal Compounds: Introduction to the Theory

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great for aspiring theoreticians...

Electronic Structure and Properties of Transition Metal Compounds: Introduction to the Theory
Isaac B. Bersuker
Manufacturer: Wiley-Interscience
ProductGroup: Book
Binding: Hardcover

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Electronic Structure: Basic Theory and Practical Methods

ASIN: 0471130796

Book Description

Covering all the latest developments, and applying the theory of electronic structure to problem solving at every opportunity, Electronic Structure and Properties of Transition Metal Compounds places the reader at the cutting edge of this important field of research. The book focuses on the electronic structure and related properties of coordination compounds, essentially treating chemical bonding as an electronic phenomenon. It also covers the central concepts of quantum chemistry and atomic states, examines theories of electronic structure and vibronic coupling, and explores physical methods of investigation. The applications of the theory to stereochemistry and crystal chemistry, electron transfer and electron-conformational effects, and reactivity and catalytic action are also discussed.

Customer Reviews:

great for aspiring theoreticians..........1998-01-16

I think this book is excellent. It covers much of the theory relative to vibrational coupling in molecules, and is very readable.

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